6063铝合金表面点状物的分析研究

利用金相显微镜(OM)、扫描电子显微镜(SEM)和能谱分析仪(EDS)等分析研究了6063铝合金表面点状凸起物的表面形貌及成分.结果表明,这种点状凸起物主要是由大量聚集的碳化硅颗粒以及少量的游离硅组成,碳化硅颗粒硬度较大,不易加工,从而造成铝合金表面异常.     

Synthesis of aluminum nitride in a coke-calcium reduction bed using nitrogen in air

An experimental study on the heating of a mixture of aluminum and lithium hydroxide (LiOH) powders in a reductive bed under air atmosphere is reported. The formation of aluminum nitride (AlN) during this process was the focus of this study. The formation of AlN was achieved using LiOH as an additive and heating the sample in a resistance furnace in a specially designed double crucible within a bed of a mixture of coke and filamentous calcium. The temperature range of the reaction was between 700°C and 1100°C. The optimum tem-perature of 1100°C and the optimum LiOH amount (5wt%) required to achieve maximum yield were determined by powder X-ray diffrac-tion (XRD) analysis. Scanning electron microscopy (SEM) micrographs clearly indicated the transformation of grain structures from rods (700°C) to cauliflower shapes (1100°C).     

冷风油雾润滑对TC4铣削过程刀-屑摩擦的影响

通过钛合金TC4的铣削实验,研究冷风油雾润滑介质特性及其施加方式对刀具-切屑摩擦行为的影响.冷风油雾喷嘴布置在刀具将要切入工件前的空行程中,其润滑效果最好.当出油量增加到一定值(约12mL·h-1)时,刀具-切屑平均摩擦系数不再发生明显变化.随着钛合金TC4铣削速度的提高,冷风干切削的平均摩擦系数增大,而冷风油雾切削的平均摩擦系数变化不明显,且远低于冷风干切削的平均摩擦系数.结果表明:油雾载体速度和刀具转速存在一定的匹配关系,使润滑效果达到最优.     

Effect of Al on microstructure and mechanical properties of as-extruded Mg–1Mn alloy sheet

The effect of Al addition on microstructure and mechanical properties of hot extruded Mg–1 Mn alloy sheet was investigated. The results revealed that the dynamic recrystallization was promoted by increasing Al content. The ultimate tensile strength and yield strength of the alloy increased with the increase of Al content. The Mg–9 Al–1 Mn alloy exhibited the highest strength, with tensile strength of 308 MPa, 307 MPa, 319 MPa, yield strength of 199 MPa, 207 MPa, 220 MPa and the elongation of 20.9%, 20.1%, 19.2% in 0°, 45°, 90°, respectively.The high strength was mainly attributed to the formation of fine dynamically recrystallized grains and large amounts of the second phase. The strengthening mechanism of the alloys was explained.     

Microstructure,mechanical properties and wear resistance of an Al–Mg–Si alloy produced by equal channel angular pressing

Microstructure, mechanical properties and wear resistance in an ultrafine-grained Al–Mg–Si alloy fabricated utilizing a combination of equal channel angular pressing (ECAP) and dynamic aging were investigated in this paper. The results indicated that the grain size of the ECAP alloy was significantly refined, i.e., to ~239 nm after three ECAP passes. Meanwhile, the yield and tensile strength of the ECAPed material reached 340 MPa and 445 MPa, respectively, while maintaining a significant uniform elongation of 14%. Wear resistance results demonstrated that the wear rate, wear depth and width of the ECAPed material decreased in comparison with the solution-treated (SST) and peak-aged (T6) conditions under a load range of 5–25 N. The adhesive wear that occurs in the undeformed specimens at 10 N does not appear in the ECAPed specimen at the same load, indicating that the ECAPed specimen delay the appearance of more serious wear mechanisms under certain loads. The cooperative interaction of high density nano-scale β" precipitates and dislocations resulted in a combination of super-high strength and good work hardening ability which suppressed the extension of cracks between the friction layer and the plastic deformation zone. As a consequence, the combination of ECAP and dynamic aging brings a significant improvement for antifriction performance of the 6061 aluminum alloy.     

D4-δ-盖及其应用

引入了D₄-δ-盖的概念,即称(F,g)为模M的D₄-δ-盖,若F是D₄-模,g是F到M的满同态,且Ker(g)《_δF.研究了D₄-δ-盖的性质以及它与投射δ-盖之间的联系,并用D₄-δ-盖刻画了δ-完备环(半完备环,半正则环).     

单取代1,3-[2H,4H]-异喹啉二酮的合成

四氢异喹啉类生物碱在自然界分布广泛且活性多样,使得这一结构成为有机合成的热点,然而在众多的有机合成方法学中,绝大多数报道都是围绕着四氢异喹啉C-1位的官能团化,对C-4位活化的方法较少,本文从1,3-[2H,4H]-异喹啉二酮出发经过两步反应即可得到4-取代的1,3-[2H,4H]-异喹啉二酮,并以1HNMR,13CNMR和HRMS确定其化学结构。产物1,3-[2H,4H]-异喹啉二酮可以根据文献报道方法得到4-取代四氢异喹啉化合物,为4-取代的四氢异喹啉类化合物的合成提供了一条便捷的路径。     

Heusler合金Fe_2VAl的晶体结构与热电性能研究

采用真空电弧熔炼和放电等离子烧结技术制备了Full-Heusler合金Fe_2VAl,利用XRD、XPS对合金的物相结构与成分进行表征,在300～800K温度区间内测试了合金的Seebeck系数、电阻率、热导率等热电参数,并将实验结果与基于L2_1有序结构Fe_2VAl合金的模拟计算值进行了比较。结果表明,实验所制的合金样品中Fe、Al、V原子比接近于2∶1∶1,基本满足Fe_2VAl合金的成分配比;结合XRD衍射谱及10K下合金的饱和磁矩可知,所制合金样品中除了完全有序的L2_1结构相外,还存在部分的B2相。另一方面,基于热电性能测试结果可知,所制Fe_2VAl合金表现出典型的n型半导体特性,其Seebeck系数和电阻率随着温度的升高而降低,这与利用VASP和BoltzTraP软件包结合计算得到的L2_1结构Fe_2VAl合金的热电参数随温度(300～800K)的变化趋势相符合;合金的热导率随着温度的升高呈先降低后升高的趋势,在500K附近具有极小值,而无量纲参数热电优值ZT在500K附近达到最大值,约为0.052。     

不同NiCo_2O_4晶体形貌对其超电容性能的影响

采用一步溶剂热法制备出尖晶石型NiCo_2O_4样品.该方法一次成型,反应后不需再次煅烧,简单易操作,可实现大批量合成.采用Raman、XRD、FT-IR和SEM对其进行表征,并采用循环伏安(CV)、恒电流充放电(GCD)及交流阻抗(EIS)对其电化学性能进行分析,探索反应时间对NiCo_2O_4晶体的形貌和超电容性能的影响.结果表明:在120℃下反应12h时,得到的NiCo_2O_4晶体为微纳米球形结构,其具有良好的电化学性能,且可逆性较好.在0.5A/g时,放电比电容达504.58F/g,经过1000次循环,其放电比电容保持率约为82%.     

AVS的发展现状及其应用前景

本文叙述了数字视音频压缩技术的发展历史和现状,着重分析了我国自主研制的视音频压缩标准AV S及其关键技术,以及采用AV S标准对我国的数字电视等音视频产业等产生的重大影响。